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We have developed a mid-infrared Doppler-free saturation absorption spectroscopy apparatus that employs a commercial continuous-wave optical parametric oscillator (CW OPO), complemented by a home-built automation and wavelength scanning system. Here, we report a comprehensive spectral scan of the Q branch transitions of theν3 = 1 band of methane (CH4) with an average linewidth (FWHM) of 4.5 MHz. The absolute frequency calibration was achieved using previously reported transition frequencies determined using optical frequency combs, while a Fabry–Perot etalon was used for the relative frequency calibration. We report 15 transitions with improved accuracies of 1.13 MHz (3.76 × 10−5 cm−1).more » « less
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Jones, Ian W.; Bersson, Jonathan S.; Liu, Jinjun; Sharma, Ketan; Vasilyev, Oleg A.; Miller, Terry A.; Stanton, John F. (, The Journal of Physical Chemistry A)
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